(A) 1s < 2p < 3d < 4s
(B) 1s < 2s = 2p < 3s = 3p
(C) 1s < 2s < 2p < 3s < 3p
(D) 1s < 2s < 4s < 3d
Choose the correct answer from the options given below:
In hydrogen atom, energy depends only on principal quantum number (n), not on l value.
Energy order:
1s < (2s = 2p) < (3s = 3p = 3d) < (4s = 4p = 4d = 4f)
1s < 2p < 3d < 4s ✔
Correct energy order → Correct
1s < 2s = 2p < 3s = 3p ✔
Matches hydrogen energy rule → Correct
2s < 2p ❌ (same energy in H atom)
Hence sequence is wrong → Incorrect
4s < 3d ❌ (n = 4 orbitals have higher energy than n = 3)
Hence sequence is wrong → Incorrect
Correct Answer = (C) and (D) only