Q. Which of the following is/are not correct with respect to energy of
atomic orbitals of hydrogen atom?
(A) 1s < 2p < 3d < 4s
(B) 1s < 2s = 2p < 3s = 3p
(C) 1s < 2s < 2p < 3s < 3p
(D) 1s < 2s < 4s < 3d
Choose the correct answer from the options given below:
A. (A) and (B) only
B. (A) and (C) only
C. (B) and (D) only
D. (C) and (D) only
Explanation
Key concept: Energy of orbitals in hydrogen atom
In hydrogen atom, energy depends only on principal quantum number (n),
not on l value.
Energy order:
1s < (2s = 2p) < (3s = 3p = 3d) < (4s = 4p = 4d = 4f)
Check option (A)
1s < 2p < 3d < 4s ✔
Correct energy order → Correct
Check option (B)
1s < 2s = 2p < 3s = 3p ✔
Matches hydrogen energy rule → Correct
Check option (C)
2s < 2p ❌ (same energy in H atom)
Hence sequence is wrong → Incorrect
Check option (D)
4s < 3d ❌ (n = 4 orbitals have higher energy than n = 3)
Hence sequence is wrong → Incorrect
Correct Answer = (C) and (D) only