For n = 4, azimuthal quantum number (l) can have values:
l = 0, 1, 2, 3
For a given value of l, magnetic quantum number ml varies from −l to +l.
The given condition is ml = 0.
For each value of l (0, 1, 2, 3), ml = 0 is allowed.
Thus, number of orbitals having ml = 0 for n = 4 is:
Total orbitals = 4
Correct Answer = 4
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