sp² Hybridization in Central Atoms | JEE Main Chemical Bonding

sp² Hybridization of Central Atoms

Question:
In which one of the following pairs the central atoms exhibit sp² hybridization?

(A) BF3 and NO2
(B) NH2 and BF3
(C) NH2 and H2O
(D) H2O and NO2

Correct Answer: BF3 and NO2

Explanation

BF3:
Boron forms three σ bonds and has no lone pair. Electron geometry is trigonal planar → sp² hybridization.

NO2 (Nitrite ion):
Nitrogen forms two σ bonds and has one lone pair. Total electron domains = 3 → sp² hybridization.

NH2: sp³ hybridized

H2O: sp³ hybridized

Hence, the correct pair with sp² hybridization is BF3 and NO2.

Updated for JEE Main 2026: This PYQ is important for JEE Mains, JEE Advanced and other competitive exams. Practice more questions from this chapter.

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