Among H₂S, H₂O, NF₃, NH₃ and CHCl₃ identify the molecule with lowest dipole moment
Q. Among H2S, H2O, NF3, NH3 and CHCl3, identify the molecule (X) with lowest dipole moment value. The number of lone pairs of electrons present on the central atom of the molecule (X) is :
A. 3
B. 2
C. 0
D. 1
Correct Answer: 1

Explanation

Dipole moment depends on both electronegativity difference and molecular geometry. Among the given molecules, NF3 has the lowest dipole moment because the N–F bond dipoles oppose the direction of the lone pair dipole on nitrogen.

Due to this cancellation effect, NF3 has a smaller net dipole moment than NH3, H2O, H2S and CHCl3.

In NF3, the central atom nitrogen has one lone pair of electrons.

Hence, the required number of lone pairs on the central atom is 1.

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