Step 1: Use boiling point elevation formula
\[ \Delta T_b = K_b \times m \]
\[ 0.5 = 5.0 \times m \]
\[ m = \frac{0.5}{5} \]
\[ m = 0.1 \text{ mol kg}^{-1} \]
Step 2: Calculate moles of solute
Mass of solvent = 150 g = 0.150 kg
\[ m = \frac{n_{solute}}{kg_{solvent}} \]
\[ 0.1 = \frac{n}{0.150} \]
\[ n = 0.015 \text{ mol} \]
Step 3: Moles of solvent
Molar mass of solvent = 300 g mol⁻¹
\[ n_{solvent} = \frac{150}{300} \]
\[ = 0.5 \text{ mol} \]
Step 4: Relative lowering in vapour pressure
For dilute solution:
\[ \frac{\Delta P}{P^0} = X_{solute} \]
\[ X_{solute} = \frac{n_{solute}}{n_{solute} + n_{solvent}} \]
\[ = \frac{0.015}{0.015 + 0.5} \]
\[ = \frac{0.015}{0.515} \]
\[ \approx 0.029 \]
Express in form ______ × 10⁻2:
\[ 0.029 = 2.9 \times 10^{-2} \]
Nearest integer = 3
Final Answer = 3
Updated for JEE Main 2026: This PYQ is important for JEE Mains, JEE Advanced and other competitive exams. Practice more questions from this chapter.