Density of 3 M NaCl solution – JEE Main Previous Year Question

Molality of NaCl Solution

Q. Density of 3 M NaCl solution is 1.25 g/mL. The molality of the solution is:
A. 2.79 m
B. 2 m
C. 1.79 m
D. 3 m
Step 1: Consider 1 litre of solution
Molarity = 3 M ⇒ moles of NaCl = 3

Step 2: Density = 1.25 g/mL
Mass of 1 L solution = 1.25 × 1000 = 1250 g

Step 3: Molar mass of NaCl = 58.5 g/mol
Mass of NaCl = 3 × 58.5 = 175.5 g

Step 4: Mass of solvent (water)
= 1250 − 175.5 = 1074.5 g = 1.0745 kg

Step 5: Molality = moles of solute / kg of solvent
= 3 / 1.0745 ≈ 2.79 m

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Updated for JEE Main 2026: This PYQ is important for JEE Mains, JEE Advanced and other competitive exams. Practice more questions from this chapter.

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