The correct statements from the following are
Q. The correct statements from the following are :

A. Ionic radii of trivalent cations of group 13 elements decreases down the group.

B. Electronegativity of group 13 elements decreases down the group.

C. Among the group 13 elements, Boron has highest first ionisation enthalpy.

D. The trichloride and triiodide of group 13 elements are covalent in nature.

Choose the correct answer from the options given below :
A. B and D Only
B. C and D Only
C. A and D Only
D. A and C Only
Correct Answer: C and D Only

Explanation

Statement A is incorrect. In group 13, although atomic size increases down the group, the ionic radii of trivalent cations do not decrease regularly. Due to poor shielding by d and f electrons in heavier elements like Ga and In, the ionic radii show irregular trend instead of continuous decrease.

Statement B is incorrect. Electronegativity does not continuously decrease down group 13. After aluminium, electronegativity slightly increases due to ineffective shielding of d and f electrons, which increases effective nuclear charge.

Statement C is correct. Boron has the highest first ionisation enthalpy among group 13 elements because of its small atomic size and strong attraction between nucleus and valence electrons.

Statement D is correct. The trihalides such as $BCl_3$, $AlCl_3$ and corresponding triiodides form covalent bonds due to high polarising power of small and highly charged $M^{3+}$ ions.

Hence, the correct statements are C and D.

Related JEE Main Questions

Updated for JEE Main 2026: This PYQ is important for JEE Mains, JEE Advanced and other competitive exams. Practice more questions from this chapter.

Scroll to Top