Molar mass of H2SO4 is:
\[ 2(1) + 32 + 4(16) = 98\ \text{g mol}^{-1} \]
From 100 g of 98% (w/w) H2SO4 solution:
Mass of H2SO4 = 98 g
Mass of water = 2 g
Moles of H2SO4 = \( \frac{98}{98} = 1 \) mol
Moles of water = \( \frac{2}{18} = 0.111 \) mol
From 100 g of 49% (w/w) H2SO4 solution:
Mass of H2SO4 = 49 g
Mass of water = 51 g
Moles of H2SO4 = \( \frac{49}{98} = 0.5 \) mol
Moles of water = \( \frac{51}{18} = 2.833 \) mol
Total moles of H2SO4 = \(1 + 0.5 = 1.5\) mol
Total moles of water = \(0.111 + 2.833 = 2.944\) mol
Total moles in solution = \(1.5 + 2.944 = 4.444\) mol
Mole fraction of H2SO4 is:
\[ X_{\text{H}_2\text{SO}_4} = \frac{1.5}{4.444} \approx 0.337 \]
Hence, the mole fraction of H2SO4 in the resultant solution is 0.337.
Updated for JEE Main 2026: This PYQ is important for JEE Mains, JEE Advanced and other competitive exams. Practice more questions from this chapter.