X-ray Spectra and Moseley’s Law | JEE Mains PYQ 2025 | Structure of Atom
Q. Given below are two statements about X-ray spectra of elements:

Statement (I): A plot of √ν (ν = frequency of X-rays emitted) vs atomic mass is a straight line.

Statement (II): A plot of ν (ν = frequency of X-rays emitted) vs atomic number is a straight line.

In the light of the above statements, choose the correct answer from the options given below:

A. Statement I is false but Statement II is true
B. Both Statement I and Statement II are true
C. Statement I is true but Statement II is false
D. Both Statement I and Statement II are false
Explanation
Step 1: Moseley’s Law

According to Moseley’s law:
√ν = a (Z − b)
where Z = atomic number

Step 2: Analysis of Statement I

Statement I relates √ν with atomic mass.
Moseley’s law depends on atomic number, not atomic mass.
✘ Statement I is false.

Step 3: Analysis of Statement II

Statement II claims ν vs atomic number is a straight line.
From Moseley’s law, √ν (not ν) is linearly related to Z.
Hence ν vs Z is not linear.
✘ Statement II is false.

Correct Answer = Both Statement I and Statement II are false

Updated for JEE Main 2026: This PYQ is important for JEE Mains, JEE Advanced and other competitive exams. Practice more questions from this chapter.

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