Q. Heat treatment of muscular pain involves radiation of wavelength of about
900 nm. Which spectral line of hydrogen atom is suitable for this?
Given:
Rydberg constant, RH = 105 cm−1
h = 6.6 × 10−34 J s, c = 3 × 108 m/s
Choose the correct answer from the options given below:
A. Lyman series, ∞ → 1
B. Balmer series, ∞ → 2
C. Paschen series, 5 → 3
D. Paschen series, ∞ → 3
Explanation
Step 1: Identify wavelength region
Given wavelength ≈ 900 nm lies in the infrared region.
Step 2: Hydrogen spectral series
Lyman series → Ultraviolet (n = 1)
Balmer series → Visible (n = 2)
Paschen series → Infrared (n = 3)
Step 3: Series limit calculation
For Paschen series (∞ → 3):
1/λ = RH (1/3² − 0) = RH/9
λ = 9 / RH = 9 × 10−5 cm = 900 nm
✔ This exactly matches the required wavelength.
Correct Answer = Paschen series, ∞ → 3