Q. Compare the energies of following sets of quantum numbers for multielectron system.
(A) n = 4, l = 1
(B) n = 4, l = 2
(C) n = 3, l = 1
(D) n = 3, l = 2
(E) n = 4, l = 0
Choose the correct answer from the options given below:
A. (E) > (C) > (A) > (D) > (B)
B. (B) > (A) > (C) > (E) > (D)
C. (C) < (E) < (D) < (A) < (B)
D. (E) < (C) < (D) < (A) < (B)
Explanation
Rule used:
For multielectron atoms, energy increases with increasing value of (n + l).
If (n + l) is same, orbital with higher n has higher energy.
(C): n + l = 3 + 1 = 4
(E): n + l = 4 + 0 = 4
(D): n + l = 3 + 2 = 5
(A): n + l = 4 + 1 = 5
(B): n + l = 4 + 2 = 6
For same (n + l): lower n → lower energy
Correct order: (C) < (E) < (D) < (A) < (B)