Electrochemistry Questions – JEE Main & NEET
Electrochemistry – Practice Questions
Q1. A constant current was passed through a solution of AuCl₄⁻ ion between gold electrodes. After 10.0 minutes, the increase in mass of cathode was 1.314 g. The total charge passed through the solution is ___ ×10⁻² F. (Given: Atomic mass of Au = 197)
Q2. The emf of the cell Tl | Tl⁺(0.001 M) || Cu²⁺(0.01 M) | Cu is 0.83 V at 298 K. It can be increased by:
increasing concentration of Tl⁺ ions
increasing concentration of Cu²⁺ ions
increasing concentration of both Tl⁺ and Cu²⁺ ions
decreasing concentration of both ions
Q3. A metal surface of area 100 cm² is coated with nickel of thickness 0.001 mm. A current of 2 A is passed through Ni(NO₃)₂ solution. Find time required in seconds. (Given: density of Ni = 10 g mL⁻¹, molar mass = 60 g mol⁻¹, F = 96500 C mol⁻¹)
Q4. Number of alkanes obtained on electrolysis of a mixture of CH₃COONa and C₂H₅COONa is:
Q5. The amount of electricity (×10⁵ C) required for oxidation of 1 mol of H₂O to O₂ is:
Q6. Which equation correctly represents change of molar conductivity with concentration for a weak electrolyte?
Λₘ − Λₘ° + A√C = 0
Λₘ²C + KₐΛₘ°² − KₐΛₘΛₘ° = 0
Λₘ − Λₘ° − A√C = 0
Λₘ²C − KₐΛₘ°² + KₐΛₘΛₘ° = 0
Q7. How can a galvanic cell be converted into an electrolytic cell?
Applying an external opposite potential greater than E°cell
Interchanging anode and cathode
Applying opposite potential less than E°cell
Reversing salt bridge direction
Q8. On charging a lead storage battery, oxidation state of Pb at anode and cathode respectively becomes:
0 → +2 and +4 → +2
+2 → 0 and 0 → +4
+2 → +4 and 0 → +2
+4 → +2 and +2 → 0
Q9. For the reaction Fe²⁺ + Ag⁺ → Fe³⁺ + Ag, the standard cell potential is:
x + 2y − 3z
x + 2y
y − 2x
z − x
Q10. Aluminium chloride solution is electrolysed for 30 minutes using 2 A current. Amount of aluminium deposited is:
1.660 g
1.007 g
0.336 g
0.112 g
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